Multilayer ceramic capacitor

ABSTRACT

A multilayer ceramic capacitor includes a multilayer body including an inner layer portion including dielectric layers and internal electrode layers alternately laminated therein, two outer layer portions respectively provided on both sides of the inner layer portion in a lamination direction, and two side gap portions respectively provided on both side surfaces of the inner layer portion and the outer layer portions, in a width direction intersecting the lamination direction, and external electrodes respectively provided on both end surfaces of the multilayer body in a length direction intersecting the lamination direction and the width direction, and each connected to the internal electrode layers, wherein nickel and magnesium are segregated between the side gap portions and the outer layer portions.

CROSS REFERENCE TO RELATED APPLICATIONS

This application claims the benefit of priority to Japanese PatentApplication No. 2020-166436 filed on Sep. 30, 2020. The entire contentsof this application are hereby incorporated herein by reference.

BACKGROUND OF THE INVENTION 1. Field of the Invention

The present invention relates to a multilayer ceramic capacitor.

2. Description of the Related Art

Conventionally, a multilayer ceramic capacitor is manufactured toinclude external electrodes at both ends of a multilayer body includingside gap portions on both side surfaces of a laminate chip includinginternal electrodes and dielectrics laminated therein (see JapaneseUnexamined Patent Application Publication No. 2018-148117).

Recently, it has been demanded that such a multilayer ceramic capacitorhas high moisture resistance from the viewpoint of durability.

SUMMARY OF THE INVENTION

Preferred embodiments of the present invention provide multilayerceramic capacitors each with high moisture resistance.

A preferred embodiment of the present invention provides a multilayerceramic capacitor that includes a multilayer body including an innerlayer portion including dielectric layers and internal electrode layersalternately laminated therein, two outer layer portions respectivelyprovided on both sides of the inner layer portion in a laminationdirection, and two side gap portions respectively provided on both sidesurfaces of the inner layer portion and the outer layer portions, in awidth direction intersecting the lamination direction, and externalelectrodes respectively provided on both end surfaces of the multilayerbody in a length direction intersecting the lamination direction and thewidth direction, and each connected to the internal electrode layers,wherein nickel and magnesium are segregated between the side gapportions and the outer layer portions.

According to preferred embodiments of the present invention, it ispossible to provide multilayer ceramic capacitors each with highmoisture resistance.

The above and other elements, features, steps, characteristics andadvantages of the present invention will become more apparent from thefollowing detailed description of the preferred embodiments withreference to the attached drawings.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a schematic perspective view of a multilayer ceramic capacitor1 according to a preferred embodiment of the present invention.

FIG. 2 is a cross-sectional view taken along the line II-II of themultilayer ceramic capacitor 1 shown in FIG. 1.

FIG. 3 is a cross-sectional view taken along the line III-III of themultilayer ceramic capacitor 1 in FIG. 1.

FIG. 4 is a partially enlarged view of FIG. 3.

FIG. 5 is an enlarged view of the circled portion Q2 of FIG. 2.

FIG. 6 is a LW cross-sectional view through internal electrode layers 15of the multilayer ceramic capacitor 1.

FIG. 7 is a flowchart showing a method of manufacturing the multilayerceramic capacitor 1.

FIG. 8 is a diagram for explaining a multilayer body preparing step S1and a barrel step S2.

FIG. 9 is a diagram showing a base electrode layer forming step S3 and aplated layer forming step S4.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

Preferred embodiments of the present invention will be described indetail below with reference to the accompanying drawings.

A multilayer ceramic capacitor 1 according to a preferred embodiment ofthe present invention will be described. FIG. 1 is a schematicperspective view of the multilayer ceramic capacitor 1 of the presentpreferred embodiment. FIG. 2 is a cross-sectional view taken along theline II-II of the multilayer ceramic capacitor 1 shown in FIG. 1. FIG. 3is a cross-sectional view taken along the line of the multilayer ceramiccapacitor 1 in FIG. 1.

The multilayer ceramic capacitor 1 has a rectangular or substantiallyrectangular parallelepiped shape, and includes a multilayer body 2, anda pair of external electrodes 3 provided at both ends of the multilayerbody 2. The multilayer body 2 includes an inner layer portion 11including a plurality of sets of dielectric layers 14 and internalelectrode layers 15.

In the following description, as terms representing the orientations ofthe multilayer ceramic capacitor 1, a direction in which the pair ofexternal electrodes 3 are provided is defined as a length direction L. Adirection in which the dielectric layers 14 and the internal electrodelayers 15 are laminated (stacked) is defined as a lamination (stacking)direction T. A direction intersecting both the length direction L andthe lamination direction T is defined as a width direction W. In thepresent preferred embodiment, the width direction is perpendicular orsubstantially perpendicular to both the length direction L and thelamination direction T.

Furthermore, a cross-section extending in the length direction L and thelamination direction T is defined as an LT cross-section, across-section extending in the length direction L and the widthdirection W is defined as an LW cross-section, and a cross-sectionextending in the width direction W and the lamination direction T isdefined as a WT cross-section. FIG. 2 is an LT cross-sectional view atthe middle portion in the width direction W of the multilayer ceramiccapacitor 1. FIG. 3 is a WT cross-section at the middle portion in thelength direction L of the multilayer ceramic capacitor 1.

Furthermore, among the six outer surfaces of the multilayer body 2, apair of outer surfaces opposing each other in the lamination direction Tis defined as a first main surface A1 and a second main surface A2, apair of outer surfaces opposing each other in the width direction W isdefined as a first side surface B1 and a second side surface B2, and apair of outer surfaces opposing each other in the length direction L isdefined as a first end surface C1 and a second end surface C2.

When it is not necessary to particularly distinguish the first mainsurface A1 and the second main surface A2 from each other, they arecollectively referred to as the main surface A, when it is not necessaryto particularly distinguish between the first side surface B1 and thesecond side surface B2, they are collectively referred to as a mainsurface B, and when it is not necessary to particularly distinguishbetween the first end surface C1 and the second end surface C2, they arecollectively referred to as an end surface C.

The dimension of the multilayer ceramic capacitor 1 is not particularlylimited. However, for example, it is preferable that the dimension inthe length direction L is about 0.2 mm or more and about 1.2 mm or less;the dimension in the width direction W is about 0.1 mm or more and about0.7 mm or less, and the dimension in the lamination direction T is about0.1 mm or more and about 0.7 mm or less.

Multilayer Body 2

The multilayer body 2 includes a laminate chip 10, and side gap portions20 provided on both sides in the width direction W of the laminate chip10. In the multilayer body 2, ridge portions R1 of the two surfaces ofthe main surface A, the side surface B, and the end surface C arechamfered and rounded.

Laminate Chip 10

The laminate chip 10 includes the inner layer portion 11, an upper outerlayer portion 12 a in the vicinity of the first main surface A1 of theinner layer portion 11, and a lower outer layer portion 12 b in thevicinity of the second main surface A2 of the inner layer portion 11.When it is not necessary to particularly distinguish between the upperouter layer portion 12 a and the lower outer layer portion 12 b, theyare collectively referred to as an outer layer portion 12.

Inner Layer Portion 11

The inner layer portion 11 includes the plurality of sets of dielectriclayers 14 and internal electrode layers 15 which are alternatelylaminated along the lamination direction T.

Dielectric layer 14

The dielectric layers 14 each preferably have a thickness of, forexample, about 0.4 μm or more and about 1.0 μm or less, and morepreferably, about 0.4 μm or more and about 0.6 μm or less.

The dielectric layers 14 are each made of a ceramic material. As theceramic material, for example, a dielectric ceramic including BaTiO₃ asa main component is used. The number of dielectric layers 14 of thelaminate chip 10 in addition to the upper outer layer portion 12 a andthe lower outer layer portion 12 b is preferably, for example, 15 ormore and 700 or less.

In the present preferred embodiment, the dielectric layers 14 do notinclude Ni (nickel), or alternatively, the Ni content in the dielectriclayers 14 is less than the Ni content in the outer layer portion 12.Thus, it is possible to increase the size of the particles of thedielectrics in the dielectric layers 14, such that it is possible toincrease the capacitance.

Internal Electrode Layer 15

The internal electrode layer 15 preferably has a thickness of, forexample, about 0.2 μm or more and about 0.8 μm or less. The number ofthe internal electrode layers 15 is preferably, for example, 15 or moreand 700 or less.

The average thickness of each of the plurality of internal electrodelayers 15 and the plurality of dielectric layers 14 is measured asfollows. First, a cross section perpendicular or substantiallyperpendicular to the length direction L of the multilayer body 2 exposedby polishing is observed by a scanning electron microscope. Next, thethicknesses of the total of five lines including a center line along thelamination direction T passing through the center of the cross-sectionof the multilayer body 2, and two lines respectively drawn on both sidesat equal or substantially equal intervals from the center line aremeasured. The average of these five measurements is calculated. Toobtain a more accurate average thickness, the above five measurementsare obtained at each of the upper portion, the middle portion, and thelower portion in the lamination direction T are obtained, and theaverage value of these measurements is used as the average thickness.

The internal electrode layer 15 includes a plurality of first internalelectrode layers 15A and a plurality of second internal electrode layers15B. The first internal electrode layers 15A and the second internalelectrode layers 15B are alternately provided. When it is not necessaryto particularly distinguish between the first internal electrode layer15A and the second internal electrode layer 15B, they will becollectively referred to as an internal electrode layer 15.

The first internal electrode layers 15A each include a first opposingportion 152 a facing the second internal electrode layer 15B, and afirst lead-out portion 151 a extending from the first opposing portion152 a toward the first end surface C1. The end portion of the firstlead-out portion 151 a is exposed to the first end surface C1, andelectrically connected to the first external electrode 3A to bedescribed later.

The second internal electrode layers 15B each include a second opposingportion 152 b facing the first internal electrode layer 15A, and asecond lead-out portion 151 b extending from the second opposing portion152 b toward the second end surface C2. The end portion of the secondlead-out portion 151 b is electrically connected to the second externalelectrode 3B to be described later.

Furthermore, a charge is accumulated in the first opposing portion 152 aof the first internal electrode layer 15A and the second opposingportion 152 b of the second internal electrode layer 15B, and thecharacteristics of the capacitor are provided.

FIG. 4 is an enlarged view of the portion Q1 of FIG. 3. As shown in FIG.4, in the WT cross-section at the middle portion in the length directionL, the positional deviation d1 between the end portions of the adjacentinternal electrode layers 15 in the width direction W is, for example,about 5 μm or less.

Furthermore, the positional deviation d2 between the end portion whichis in the vicinity of the side surface B and located outermost in thewidth direction W and the end portion which is located innermost in thewidth direction W among all of the internal electrode layers 15 is, forexample, about 10 μm or less.

That is, the end portions in the width direction W of the laminatedinternal electrode layers 15 are located at the same or substantiallythe same position in the width direction W. In other words, thepositions of the end portions are aligned or substantially aligned inthe lamination direction T.

In the present preferred embodiment, the internal electrode layers 15are, for example, made mainly of Ni (nickel) including Sn (tin).However, the present invention is not limited thereto, and the internalelectrode layers 15 may be made of, for example, a metallic materialsuch as Cu, Ag, Pd, a Ag—Pd, and Au.

Furthermore, Mg (magnesium) included in the side gap portions 20 issegregated at the side gap portions 20 on both side surfaces of theinternal electrode layers 15.

Sn-Layer 16 Extending from Internal Electrode Layer 15

FIG. 5 is an enlarged view of the circled portion Q2 of FIG. 2.

The Sn-layer 16 is provided on the surfaces of the internal electrodelayers 15. The Sn-layer 16 is formed by migrating from the inside to thesurface during firing. The Sn-layer 16 extends from the surfaces of theinternal electrode layers 15 to a boundary region Z1 between theexternal electrode 3, and the dielectric layers 14 and the internalelectrode layers 15 adjacent to one another in the lamination directionT. Furthermore, the Sn-layer 16 also covers the boundary surfaces of theinternal electrode layers 15 with the external electrode 3.

It should be noted that it is not necessary for the Sn-layer 16 to coverthe entire internal electrode layers 15, and the Sn-layer 16 can onlycover a portion of the internal electrode layers 15.

Effect of Sn-Layer 16

In the multilayer ceramic capacitor 1 of the present preferredembodiment, since the Sn-layer 16 extends to the boundary region Z1between the dielectric layers 14 and the external electrode 3, forexample, it is possible to reduce or prevent moisture through theboundary surface between the external electrode 3 and the multilayerbody 2 from flowing in the interior of the inner layer portion 11, whichprovides high humidity resistance.

In the present preferred embodiment, the Sn-layer 16 extending from oneof the internal electrode layers 15 is not coupled to the Sn-layer 16extending from another internal electrode layer 15 adjacent to the oneinternal electrode layer 15, and there is also a portion where theSn-layer 16 is not provided in the boundary region Z1 between thedielectric layer 14 and the external electrode 3. However, it issufficiently effective to improve the humidity resistance of themultilayer ceramic capacitor 1 even in such a case.

Outer Layer Portion 12

The thickness of the outer layer portion 12 is preferably about 9.5 μmor more and about 30 μm or less, and more preferably about 9.5 μm toabout 20 μm, for example, for both the upper outer layer portion 12 aand the lower outer layer portion 12 b.

Ni in Outer Layer Portion 12

Both the upper outer layer portion 12 a and the lower outer layerportion 12 b of the outer layer portion 12 are made of a dielectricceramic material including BaTiO₃ as a main component, similar to thedielectric layer 14 of the inner layer portion 11, for example. However,the upper outer layer portion 12 a and the lower outer layer portion 12b differ from the dielectric layer 14 of the inner layer portion 11 inthat the former includes Ni, or the content of Ni is higher in theformer than in the latter.

As schematically shown in FIG. 4, Ni is not provided in a region Z3 in avicinity of the internal electrode layer 15 in the outer layer portion12, since Ni is absorbed by the internal electrode layer 15. That is, Niis distributed unevenly rather than entirely in the outer layer portion12. Furthermore, the density of Ni is highest in the middle portion ofthe outer layer portion 12 in the lamination direction T.

Advantageous Effects

Since the multilayer ceramic capacitor 1 of the present preferredembodiment includes Ni in the outer layer portion 12, particles of thedielectric ceramic after firing are densified.

Furthermore, since the pores provided in the dielectric ceramic in theouter layer portion 12 are filled with Ni, humidity resistance isincreased in the multilayer ceramic capacitor 1.

Furthermore, Ni in the outer layer portion 12 is diffused into theCu-layer of the external electrode 3, such that the adhesion with theexternal electrode 3 is improved.

Although Mg is not included in the outer layer portion 12 in the presentpreferred embodiment, Mg may be included in the outer layer portion 12.

Side Gap Portion 20

The side gap portions 20 include side gap portions 20 which arerespectively provided in the vicinity of the first side surface B1 ofthe laminate chip 10 and the second side surface B2 of the laminate chip10. When it is not necessary to particularly distinguish between thefirst side gap portion 20 a and the second side gap portion 20 b, theywill be collectively referred to as a side gap portion 20.

Component of Side Gap Portion 20

The side gap portions 20 each cover, along the end portions, the endportions in the width direction W of the internal electrode layers 15exposed at the both side surfaces of the laminate chip 10. There is aninterface U shown in FIGS. 3 and 4 between the laminate chip 10 and theside gap portion 20.

The side gap portions 20 are made of, for example, a dielectric ceramicmaterial including BaTiO₃ as a main component, similarly to thedielectric layers 14, but further include Mg as a sintering aid. Thecontent of Mg is, for example, about 0.2 mol % or more and about 2.8 mol% or less with respect to 100 moles of Ti at the middle portion in thelength direction L of the side gap portion 20. When Mg is about 2.8 mol% or less, since the grain growth of the dielectric is not reduced orprevented in the dielectric layer 14 in the vicinity of the outermostlayer of the internal electrode layers 15, a capacitance decrease isless likely to occur.

Furthermore, Mg of the side gap portion 20 and Ni of the outer layerportion 12 are segregated in a boundary region Z2 between the side gapportion 20 and the outer layer portion 12 during firing. A portion ofthe segregated Ni and a portion of the segregated Mg provides a Ni—Mgoxide.

That is, Ni—Mg oxide is segregated in the boundary region Z2. A portionof Ni segregated in the boundary region Z2 is present in the form of Niin the boundary region Z2. A portion of Mg segregated in the boundaryregion Z2 is present in the form of Mg in the boundary region Z2.Therefore, Ni—Mg oxide, Ni, and Mg are segregated in the boundary regionZ2.

Ni is not included in the dielectric layer 14. Therefore, thesegregation of Ni and Ni—Mg oxide in the boundary region between thedielectric layer 14 and the side gap portion 20 is smaller than thesegregation of Ni and Ni—Mg oxide in the boundary region Z2.

Since the dielectric layers 14 do not include Ni, the grain growth ofthe particles of the dielectric layers 14 is not reduced or prevented.Therefore, the particles of the dielectric layers 14 become large, suchthat it is possible to increase the capacitance of the multilayerceramic capacitor 1.

A Ni—Mg alloy, which is an alloy of Mg included in the side gap portion20 and Ni included in the outer layer portion 12, is segregated in theboundary region Z2 between the side gap portion 20 and the outer layerportion 12. The boundary region Z2 tends to become the penetration pathof moisture. A portion of the pores in the boundary region Z2 is filledwith Ni—Mg oxide. A portion of the pores present in the boundary regionZ2 is filled with Ni or Mg. Thus, the multilayer ceramic capacitor 1 ofthe present preferred embodiment has high humidity resistance.

Boundary Region Z2

Regarding the end portions of the internal electrode layers 15 asdescribed above, the positional deviation dl between the adjacentinternal electrode layers 15 on the WT cross-section including the widthdirection W and the lamination direction T at the middle portion in thelength direction L shown in FIG. 4, is, for example, about 5 μm less.Furthermore, the positional deviation d2 among the end portion which islocated outermost in the width direction W of the internal electrodelayer 15, the end portion which is located innermost in the widthdirection W of the internal electrode layer 15, and all of the internalelectrode layers 15, is, for example, about 10 μm or less.

The boundary region Z2 between the side gap portion 20 and the outerlayer portion 12 is a substantially band-shaped region of about 3 μm inthe width direction W around the extended line e extending in thelamination direction T on the middle in the width direction W betweenthe end portion of the internal electrode layer 15 located outermost inthe width direction W, and the end portion of the internal electrodelayer 15 located innermost in the width direction W.

The segregation of Ni—Mg oxide, the segregation of Ni, and thesegregation of Mg can be observed by WDX (wavelength-dispersive X-rayspectrometry).

External Electrode 3

The external electrodes 3 each include a first external electrode 3Aprovided on the first end surface C1 of the multilayer body 2, and asecond external electrode 3B provided on the second end surface C2 ofthe multilayer body 2. When it is not necessary to particularlydistinguish between the first external electrode 3A and the secondexternal electrode 3B, they will be collectively referred to as anexternal electrode 3. The external electrode 3 covers not only the endsurface C, but also covers portions of the main surface A and the sidesurface B which are in the vicinity of the end surface C.

As described above, the end portion of the first lead-out portion 151 aof the first internal electrode layer 15A is exposed at the first endsurface C1, and electrically connected to the first external electrodelayer 3A. Furthermore, the end portion of the second lead-out portion151 b of the second internal electrode layer 15B is exposed at thesecond end surface C2, and is electrically connected to the secondexternal electrode 3B. Thus, a plurality of capacitor elements areelectrically connected in parallel between the first external electrode3A and the second external electrode 3B.

External Electrode 3 Connection Ratio Between Internal Electrode layer15 and External Electrode 3

FIG. 6 is an LW cross-sectional view through the internal electrodelayers 15 of the multilayer ceramic capacitor 1. FIG. 3 provides a WTcross-section at a position W1 passing through the middle portion in thewidth direction W of FIG. 6. A position W2 in FIG. 6 is a positionpassing through the end portion of the internal electrode layer 15 inthe width direction W.

Since the internal electrode layers 15 are each thin, a plurality ofpores 15 a are actually extending through the lamination direction T.Therefore, when viewed in the LT cross-section as in FIG. 2, not all ofthe internal electrode layers 15 are connected to the external electrode3. As shown by position P1 in FIG. 2, the internal electrode layer 15may be separated from the external electrode 3. However, although theinternal electrode layer 15 and the external electrode 3 are notconnected to each other at the position P1, the internal electrode layer15 and the external electrode 3 are connected at a position shifted inthe width direction W from the position P1.

Here, the number of all of the internal electrode layers 15 extending toone of the external electrodes 3 in the LT cross-section shown in FIG. 2at a certain location in the width direction W in FIG. 6 is defined asN0, and the number of the internal electrode layers 15 connected to theone of the external electrodes 3 among them is defined as N. Then, theconnection ratio at the certain location is defined as N/N0.

For example, when the number of all of the internal electrode layers 15extending to one of the external electrodes 3 in the LT cross-sectionshown in FIG. 2 at the position W1 passing through the middle portion inthe width direction W in FIG. 6 is defined as N0, and the number of theinternal electrode layers 15 connected to the one of the externalelectrodes 3 among them is N1, the connection ratio at the position W1is defined as N1/N0.

Furthermore, similarly to the above, when the number of all of theinternal electrode layers 15 extending to one of the external electrodes3 in the LT cross-section shown in FIG. 2 at the position W2 passingthrough the end portions in the width direction W in FIG. 6 is definedas N0, and the number of the internal electrode layers 15 connected tothe one of the external electrodes 3 among them is defined as N2, theconnection ratio at the position W2 is defined as N2/N0.

In common multilayer ceramic capacitors that differ from the presentpreferred embodiment, for example, the connection ratio N1/N0 in the LTcross-section at the position W1 passing through the middle portion inthe width direction W, and the connection ratio N2/N0 in the LTcross-section at the position W2 passing through the end portions in thewidth direction W are greater than about 90% when expressed as apercentage. Furthermore, for example, the difference between theconnection ratio N1/N0 at the position W1 passing through the middleportion in the width direction W, and the connection ratio N2/N0 at theposition W2 passing through the end portion in the width direction W issmaller than about 10%.

When the connection ratio is smaller than about 90%, and the differencein the connection ratio differs greatly by the position, theconnectivity between the internal electrode layer 15 and the externalelectrode 3 is deteriorated, the flow of electricity is reduced orprevent or becomes unstable, such that the equivalent series resistance(ESR) of the multilayer ceramic capacitor may increase.

However, in the multilayer ceramic capacitor 1 of the present preferredembodiment, the connection ratio N1/N0 at the position W1 passingthrough the middle portion in the width direction W, and the connectionratio N2/N0 at the position W2 passing through the end portion in thewidth direction W are about 90% or more when expressed as a percentage.Furthermore, the difference between the connection ratio N1/N0 at theposition W1 passing through the middle portion in the width direction W,and the connection ratio N2/N0 at the position W2 passing through theend portion in the width direction W is about 10% or less.

Therefore, according to the multilayer ceramic capacitor 1 of thepresent preferred embodiment, the contact area between the internalelectrode layer 15 and the external electrode 3 is sufficiently secured,there is no variation in the connection ratio, a good connection ratiois ensured, electricity flows well, and the equivalent series resistance(ESR) of the multilayer ceramic capacitor can also be reduced.

Detection Method

The connection ratio between the external electrode 3 and the internalelectrode layer 15 is detected as follows.

Connection Ratio at Position W1

Polishing starts at the LT side surface of the multilayer ceramiccapacitor 1, and the internal electrode layers 15 begin to be exposed,such that the resultant LT cross-section polished about 5 μm is exposed.

Then, the number of the internal electrode layers 15 extending to one ofthe external electrodes 3 in the LT cross-section and connecting withthe one of the external electrodes 3 is defined as N1.

The total number of the internal electrode layers 15 connected to theexternal electrode 3 provided on the same side is defined as N0.

With N1 and N0 above, the connection ratio N1/N0 at the position W1 isobtained.

Connection Ratio at Position W2

Polishing starts at the LT side surface of the multilayer ceramiccapacitor 1, and continues up to the middle portion of the internalelectrode layers 15 in the width direction, such that the resultant LTcross-section is exposed.

Then, the number of the internal electrode layers 15 extending to one ofthe external electrodes 3 in the LW cross-section and connecting withthe one of the external electrodes 3 is defined as N2.

The total number of the internal electrode layers 15 connected to theexternal electrode 3 provided on the same side is defined as N0.

With N2 and N0 above, the connection ratio N2/N0 at the position W1 isobtained.

In a case in which the number of the internal electrode layers 15 islarge, it is acceptable to check about 20 pieces of the internalelectrode layers 15 in the region of the outermost layer and about 40pieces of the internal electrode layers 15 at the middle portion in thelamination direction T to obtain the number of the internal electrodelayers connected to the external electrode 3 and calculate the averagevalue.

In the multilayer ceramic capacitor 1 of the present preferredembodiment, a result of actual measurement showed that the connectionratios at the position W1 and the position W2 were about 90% or more.

The reason why it is possible to obtain high connection ratios in thisway will be described in the manufacturing method described later.

Structure of External Electrode 3

The external electrode 3 includes a base electrode layer 30 and a platedlayer 31 in order from the multilayer body 2.

As shown in FIGS. 2 and 6, the base electrode layer 30 is divided into afirst region 30 a of, for example, about 0.1 μm to about 5 μm, a secondregion 30 b, and a third region 30 c of, for example, about 0.1 μm toabout 5 μm in order from the multilayer body 2. The thickness of thesecond region 30 b is not limited to about 0.1 μm to about 5 μm. Thethickness of the second region 30 b corresponds to the remainingthickness obtained by eliminating the first region 30 a and the thirdregion 30 c from the external electrode 3. The plated layer 31 includesa Ni plated layer 31 a and a Sn plated layer 31 b in order from the baseelectrode layer 30. The external electrode 3 including these layerscovers not only the end surface C, but also covers portions of the mainsurface A and the side surface B in the vicinity of the end surface C.

Furthermore, the first region 30 a, the second region 30 b, and thethird region 30 c may be divided according to the ratio of glass G. Forexample, in the LT cross-section, when the area ratio of glass to Cu inthe entire base electrode layer 30 (area of glass/area of Cu) is definedas P, the first region 30 a may be defined as a region of about 0.1 P orless, the second region 30 b may be defined as a region of about 1.2 Por more, and the third region 30 c may be defined as a region lower thanabout 1.0 P. It should be noted that a second region may or may not beincluded. The second region can belong to the first region or the thirdregion when the second region satisfies either one of the definedthickness or P of them.

Material of External Electrode 3

The first region 30 a, the second region 30 b, and the third region 30 cof the base electrode layer 30 are formed by firing a Cu paste in whichglass G including Ba (barium) for densification is mixed, and thus, areelectrodes by post-fire which are separately fired after the firing ofthe multilayer body 2.

First Region 30 a

The thickness of the first region 30 a in the length direction L is, forexample, about 0.1 μm or more and about 5 μm or less.

As schematically shown in FIG. 5, the first region 30 a includes Ni,which is a metal included in the internal electrode layers 15, in alarger amount than the second region 30 b and the third region 30 c.When detected by WDX, the intensity ratio of Ni to Cu is preferablyabout 20% or more, for example.

Ni is included in a higher density, in particular, on a side of thefirst region 30 a in the vicinity of the inner layer portion 11, than inthe other regions such as a side of the first region 30 a in thevicinity of the second region 30 b, the second region 30 b, and thethird region 30 c. A Ni-rich layer is provided on the side of the firstregion 30 a in the vicinity of the inner layer portion 11. Furthermore,the density of Ni near the internal electrode layers 15 in the side ofthe first region 30 a in the vicinity of the inner layer portion 11 ishigher than the density of Ni adjacent to the dielectric layers 14 inthe side of the first region 30 a in the vicinity of the inner layerportion 11. Furthermore, Ni makes a solid solution with Cu in the firstregion 30 a, and is alloyed.

As described above, the first region 30 a includes a Ni component morethan the second region 30 b and the third region 30 c. Therefore, theinternal electrode layers 15 and the base electrode layer 30 have abetter connection ratio.

Particle Size of Cu Being Large in Side in the Vicinity of MultilayerBody 2

Furthermore, the particle size of Cu in the first region 30 a is largerthan that in the second region 30 b and the third region 30 c. Inaddition, the thickness decreases as approaching the second region 30 band the third region 30 c.

The particle size of Cu is specified based on the area in the LTcross-section shown in FIG. 5.

Second Region 30 b

The second region 30 b corresponds to a region other than the firstregion 30 a and the third region 30 c. The second region 30 b ispreferably thicker than the total value of the thicknesses of the firstregion 30 a and the third region 30 c, and is, for example, about 10 μmor more and about 40 μm or less.

The second region 30 b includes more glass G than the first region 30 aand the third region 30 c. When the area ratio of glass to Cu (area ofglass/area of Cu) in the entire base electrode layer 30 in the LTcross-section is P, the glass G is, for example, equal to or larger thanabout 1.2 P. The ratio of the glass G is obtained by measuring the areaof Si by WDX, and calculating the area of Si with respect to the totalarea.

Third Region 30 c

The third region 30 c includes more Cu than the first region 30 a andthe second region 30 b. The content of the glass is, for example, lessthan about 1.0 P in the LT cross-section shown in FIG. 5.

The third region 30 c includes more Cu than the second region 30 b andthe third region 30 c. Therefore, the connection ratio when mounting themultilayer ceramic capacitor 1 on a board is favorable.

Furthermore, it is possible to determine the adhesiveness of the Niplated layer 31 a by counting portions where plating is not provided byvisually checking 100 locations on the surface of the plated layer 31.

The third region 30 c contains Cu in the greatest amount. Therefore, theNi plated layer 31 a on the outer side is easily adhered thereto.Furthermore, the plated layer 31 overall is hardly peeled off therefrom.In the present preferred embodiment, there was no portion withoutplating.

In the multilayer ceramic capacitor 1 of the present preferredembodiment, since the ratio of the glass G in the second region 30 b is,for example, about 1.2 P or more, the multilayer ceramic capacitor 1 hasa high sealability property and high moisture resistance. Regardinghumidity resistance of the multilayer ceramic capacitor 1, it wasdetermined that the humidity resistance was low when a voltage of about6.3V was applied and the resistance was below about 100 MΩ under anenvironment of temperature about 85° C. and humidity about 85%. Thethreshold of about 100 MΩ is for the case of a capacitance of about 1μF.

Unlike the present preferred embodiment, among 100 pieces of themultilayer ceramic capacitors 1 for comparison having the ratio of glassG smaller than about 1.2 P in the second region 30 b, the resistance wasbelow about 100 MΩ in eleven pieces of the multilayer ceramiccapacitors. Among 100 pieces of the multilayer ceramic capacitors 1 inthe present preferred embodiment having the ratio of glass G of equal toor larger than about 1.2 P in the second region 30 b, there was nomultilayer ceramic capacitors in which the resistance is below about 100MΩ.

As described above, the multilayer ceramic capacitor 1 of the presentpreferred embodiment has favorable moisture resistance because the ratioof the glasses G in the second regions 30 b, for example, about 1.2 P ormore.

Protective Layer 33

In the third region 30 c in the multilayer ceramic capacitor 1 of thepresent preferred embodiment, protective layers 33 including S (sulfur)and Ba (barium) are each provided on a surface of the glass G facing theNi plated layer 31 a. The protective layers 33 cover about 50% or moreof the portions containing the glass G on the surface of the thirdregion 30 c, that is, the surface of the base electrode layer 30, andpreferably cover about 70% or more thereof. The thicknesses of theprotective layers 33 are, for example, each about 10 nm or more andabout 1 μm or less.

Confirmation Method of Protective Layer 33

The protective layers 33 can be confirmed by imaging a region includingglass G, the third region 30 c, and the Ni plated layer 31 a in theregion within the region in the external electrode 3 in the LTcross-section in the middle portion in the width direction by TEM(Transmission Electron Microscope)-EDX (Energy Dispersive X-raySpectroscopy).

Thickness of Protective Layer 33

The thickness of the protective layer 33 is obtained by measuring thethicknesses of S and Ba from the glass G toward the interior of the Niplated layer 31 a based on the observed S and Ba images. When thesurface of the glass G is a curved surface, the thickness in the normaldirection is used. If the thickness varies depending on locations,average values of the regions divided into three equal portions in thelamination direction in the LT cross section may be used.

Coverage of Protective Layer 33

The coverage of the protective layer 33 can be obtained by dividing thelength of the protective layer 33 by the length of the surface of thebase electrode layer 30 including the surface of the glass G, measuredon the LT cross-section.

Plated Layer 31

The plated layer 31 includes, for example, the Ni plated layer 31 a andthe Sn plated layer 31 b in order from the base electrode layer 30.

Method of Manufacturing Multilayer Ceramic Capacitor 1

FIG. 7 provides a flowchart showing a method of manufacturing themultilayer ceramic capacitor 1.

The method of manufacturing the multilayer ceramic capacitor 1 includesa multilayer body preparing step S1 of preparing the multilayer body 2,a barrel step S2, a base electrode layer forming step S3, and a platedlayer forming step S4.

Multilayer Body Preparing Step S1

The multilayer body preparing step S1 includes a material sheetpreparing step S11, a material sheet laminating step S12, a mother blockforming step S13, a mother block cutting step S14, a side gap portionforming step S15, and the firing step S16. FIG. 8 is a diagram forexplaining the multilayer body preparing step S1 and the barrel step S2.

Material Sheet Preparing Step S11

A ceramic slurry including a ceramic powder including, for example,BaTiO₃ as a main component, a binder, and a solvent is prepared. In thepresent preferred embodiment, the ceramic slurry does not include Ni, orthe Ni content therein is smaller than that in the outer layer portions12.

The ceramic slurry is molded into a sheet shape or substantially a sheetshape using, for example, a die coater, a gravure coater, a microgravure coater, etc. on a carrier film, such that an inner layer ceramicgreen sheet 101 is manufactured.

Furthermore, an upper outer layer portion ceramic green sheet 112defining and functioning as the upper outer layer portion 12 a, and alower outer layer portion ceramic green sheet 113 defining andfunctioning as the lower outer layer portion 12 b are also manufacturedin the same or substantially the same manner.

The upper outer layer portion ceramic green sheet 112 and the lowerouter layer portion ceramic green sheet 113 are manufactured by aceramic slurry including, for example, a ceramic powder including BaTiO₃as a main component, a binder, and a solvent, similarly to the innerlayer ceramic green sheet 101. However, unlike the inner layer ceramicgreen sheet 101, the upper outer layer portion ceramic green sheet 112and the lower outer layer portion ceramic green sheet 113 include Ni, orhave a higher Ni content than the inner layer ceramic green sheet 101.

Subsequently, the conductive paste 102 including Ni, glass (Si oxide),and Sn is printed by, for example, screen-printing, ink jet printing,gravure printing, or the like, so as to have a strip-shaped pattern orsubstantially a strip-shaped pattern, on the inner layer ceramic greensheet 101.

Thus, the material sheet 103 is prepared by printing the conductivepaste 102 defining and functioning as the internal electrode layer 15 onthe surface of the inner layer ceramic green sheet 101 defining andfunctioning as the dielectric layer 14.

Material Sheet Laminating Step S12

Next, in the material sheet laminating step S12, a plurality of materialsheets 103 are laminated.

Specifically, the plurality of material sheets 103 are stacked such thatthe strip-shaped conductive pastes 102 are directed in the same orsubstantially the same direction and shifted by half pitch in the widthdirection between the adjacent material sheets 103.

Furthermore, the upper outer layer portion ceramic green sheet 112defining and functioning as the upper outer layer portion 12 a isstacked on one side of the plurality of laminated material sheets 103,and the lower outer layer portion ceramic green sheet 113 defining andfunctioning as the lower outer layer portion 12 b is stacked on theother side thereof.

Mother Block Forming Step S13

Subsequently, in the mother block forming step S13, the upper outerlayer portion ceramic green sheet 112, the plurality of stacked materialsheets 103, and the lower outer layer portion ceramic green sheet 113are subjected to thermocompression bonding. As a result, the motherblock 110 is formed.

Mother Block Cutting Step S14

Then, in the mother block cutting step S14, the mother block 110 is cutalong a cutting line X and a cutting line Y intersecting the cuttingline X corresponding to the dimension of the laminate chip 10. As aresult, the laminate chip 10 is manufactured. It should be noted that,in the present preferred embodiment, the cutting line Y is perpendicularor substantially perpendicular to the cutting line X.

Side Gap Portion Forming Step S15

Next, a ceramic slurry in which Mg is added as a sintering aid to thedielectric powder, which is the same or substantially the same as thatof the inner layer ceramic green sheet 101, is prepared. Then, theceramic slurry is applied on a resin film, and dried to manufacture aside gap portion ceramic green sheet. It should be noted that aplurality of side gap portion ceramic green sheets may be manufactured.

Then, the side gap portion ceramic green sheet is affixed on the sideportion where the internal electrode layers 15 of the laminate chip 10are exposed, such that a layer defining and functioning as the side gapportion 20 is formed.

Thus, the side gap portion 20 is affixed to the LT side surface of thelaminate chip 10, such that the multilayer body 2 in a state beforefiring is formed.

Firing Step S16

The layer defining and functioning as the side gap portion 20 is formedin the laminate chip 10, and the resultant body is subjected todegreasing treatment in a nitrogen atmosphere under a predeterminedcondition, and then fired and sintered at a predetermined temperature ina nitrogen-hydrogen-steam mixed atmosphere to form the multilayer body2.

Since the side gap portion 20 is affixed to the laminate chip 10including the dielectric layers 14, there is an interface between theside gap portion 20 and the laminate chip 10 even after firing.

Here, a Ni—Mg alloy, which is an alloy of Mg included in the side gapportion 20 and Ni included in the outer layer portion 12, is segregatedin the boundary region Z2 between the side gap portion 20 and the outerlayer portion 12. The boundary region Z2 tends to become the penetrationpath of moisture. Therefore, the pores existing in this portion arefilled, and the moisture resistance becomes high.

Here, as shown in FIG. 4, since Ni is included in the outer layerportion 12, particles of the dielectric ceramic after firing aredensified. Furthermore, since the pores provided in the dielectricceramic in the outer layer portion 12 are filled with Ni, moistureresistance of the multilayer ceramic capacitor 1 is increased.

As shown in FIG. 5, the Sn-layer 16 which has migrated from the interiorto the surface is formed on the surfaces of the internal electrodelayers 15.

Barrel Step S2

Next, barrel polishing is performed on the multilayer body 2. As aresult, the ridge portion R1 of the multilayer body 2 is rounded.

Since the internal electrode layer 15 shrinks during the firing stepS16, a portion of the internal electrode layers 15 may not be exposed atthe end surface C. However, since the barrel step S2 is provided, theend surface C of the multilayer body 2 is also polished, such that thenumber of the internal electrode layers 15 which are not exposed at theend surface C is reduced.

Furthermore, the positional deviation d2 between the end portion whichis in the vicinity of the side surface B and located outermost in thewidth direction W and the end portion which is located innermost in thewidth direction W among all of the internal electrode layers 15 is, forexample, about 10 μm or less.

That is, the end portions in the width direction W of the laminatedinternal electrode layers 15 are located at the same or substantiallythe same position in the width direction W. In other words, thepositions of the end portions are aligned or substantially aligned inthe lamination direction T.

Base Electrode Layer Forming Step S3

The base electrode layer forming step S3 includes a first region formingstep S31, a second region forming step S32, a third region forming stepS33, and a firing step S34.

FIG. 9 is a diagram showing the base electrode layer forming step S3 anda plated layer forming step S4.

First Region Formation Step S31

In the first region forming step S31, both end surfaces C of themultilayer body 2 are immersed in a glass-containing Cu paste to formthe first region 30 a. To form the first region 30 a, the Cu pasteincluding Cu particles having a small particle size is used. Theparticle size of the Cu particles is, for example, about 0.05 μm or moreand about 3 μm or less. Furthermore, it is preferable that the thicknessis, for example, about 0.05 μm or more and about 1 μm or less.

Here, the positional deviation d of the internal electrode layers 15 inthe vicinity of the end surface C is smaller in the barrel step.However, there is a possibility that the positional deviation d remainssomewhat in the internal electrode layers 15 in the vicinity of the endsurface C.

In the present preferred embodiment, since the Cu paste having a smallparticle size is used, the Cu paste can enter the portion of thepositional deviation d remaining in the internal electrode layers 15 inthe vicinity of the end surface C, leading to the favorable contact withthe internal electrode layers 15.

Second Region Forming Step S32

Next, in the second region forming step S32, both end surfaces C of themultilayer body 2 are immersed in Cu pastes, each having a higher glasscontent than that of the first region 30 a and the third region 30 c, toform the second region 30 b.

The second region 30 b includes more glass G than the first region 30 aand the third region 30 c. In the LT cross-section, when the area ratioof glass to Cu in the entire base electrode layer 30 (area of glass/areaof Cu) is defined as P, the second region 30 b may be defined as aregion of, for example, about 1.2 P or more. Since the ratio of theglass G in the second region 30 b is about 1.2 P or more, the sealingproperty and the moisture resistance are improved.

However, in order to reduce or prevent the deterioration of theconductivity of the second region 30 b, the ratio of the glasses G inthe second region 30 b is preferably, for example, about 2.5 P or less.

It should be noted that the particle size of the Cu particles includedin the Cu paste may be the same or substantially the same as theparticle size of the Cu particles included in the Cu paste, or may belarger than the particle size of the Cu particles included in the Cupaste.

Third Region Forming Step S33

Next, in the third region forming step S33, both end surfaces C of themultilayer body 2 are immersed in a Cu paste having a higher Cu contentthan the Cu pastes of the second region 30 b and the third region 30 c,to form the third region 30 c. The Cu paste 118 includes glass G. Theglass G includes, for example, BaO—B₂O₃—SiO₂ glass orBaO—B₂O₃—SiO₂—LiO—NaO glass including Ba. In addition, sulfur (S) isincluded in the glass G.

Firing Step S34

Then, the resultant body is heated for a predetermined time in anitrogen atmosphere at a set firing temperature. As a result, the baseelectrode layer 30 is burned onto the multilayer body 2.

At this time, the Sn-layer 16 formed on the surfaces of the internalelectrode layers 15 extends from the surfaces of the internal electrodelayers 15 to the boundary region Z1 between the external electrode 3,and the internal electrode layers 15 and the dielectric layers 14adjacent to the internal electrode layers 15 in the lamination directionT.

Furthermore, as schematically shown in FIG. 5, Cu in the first region 30a is coupled, and the mass of Cu is larger than the second region 30 band the third region 30 c, such that the thickness in the laminationdirection T is larger than the thickness of the internal electrodelayers 15.

Plated Layer Forming Step S4

The plated layer forming step S4 includes a Ni plated layer forming stepS41, and a Sn plated layer forming step S42.

Ni Plated Layer Forming Step S41

In the Ni plated layer forming step S41, the third region 30 c of thebase electrode layer 30 is immersed in a plating solution for formingthe plated layer 31, to form the Ni plated layer 31 on the outerperiphery of the external electrode 3.

At this time, the third region 30 c includes more Cu than the firstregion 30 a and the second region 30 b. The amount of Cu can be measuredby calculating the area of Cu detected by WDX. The third region 30 cincludes more Cu than the second region 30 b and the third region 30 c.Therefore, the connection ratio when mounting the multilayer ceramiccapacitor 1 on a board is preferable.

Here, when the third region 30 c of the base electrode layer 30 isimmersed in a process liquid in which the plating solution and S(sulfur) are mixed, the mixed process liquid containing the platingsolution and S erodes the glass G which is exposed at the surface of thethird region 30 c.

However, according to the present preferred embodiment, since the glassG includes S and Ba, the S and Ba begin to gradually form the protectivelayer 33 on the surface of the glass G on which the erosion by theplated layer 31 is progressing.

When the formation of the protective layer 33 progresses, the erosion ofthe glass G by the plating solution is gradually reduced or prevented,and once the protective layer 33 is formed to have a predeterminedthickness, the glass G is hardly eroded.

On the other hand, unlike the present preferred embodiment, if theprotective layer 33 is not formed, the plating solution continues toerode the glass G, and advances to the second region 30 b and the firstregion 30 a in the interior of the base electrode layer 30.

However, according to the present preferred embodiment, at an initialstage in which the third region 30 c of the base electrode layer 30 isimmersed in the plating solution in this way, the protective layer 33 isformed by the process liquid including Ba and S included in the glass G.Furthermore, the protective layer 33 defining and functioning as abarrier of the glass G to the plating solution, and thus, furthererosion of the glass G by the plating solution is reduced or prevented.

Therefore, it is possible to obtain the multilayer ceramic capacitor 1in which the erosion of the base electrode layer 30 by the platingsolution is small, and the heat resistance, the water resistance, andthe moisture resistance are high.

The third region 30 c includes Cu in the most amount. Therefore, the Niplated layer 31 a on the outer side is easily adhered thereto.Furthermore, the plated layer 31 overall is hardly peeled off therefrom.

Sn Plated Layer Forming Step S42

Then, the Sn plated layer 31 b is formed on the outer side of the Niplated layer 31 a.

Through the above steps, the multilayer ceramic capacitor 1 of thepresent preferred embodiment is manufactured. Although preferredembodiments of the present invention have been described above, thepresent invention is not limited to this preferred embodiment, andvarious modifications may be made within the scope thereof.

For example, in the present preferred embodiment, the base electrodelayer 30 is provided with the three regions. However, the presentinvention is not limited to this, and the base electrode layer 30 mayinclude only the first region 30 a and the third region 30 c without thesecond region 30 b. Furthermore, the base electrode layer 30 may includeonly one region.

In the present preferred embodiment, the base electrode layer 30including the three regions is manufactured by three coating steps ofthe first region forming step S31, the second region forming step S32,and the third region forming step S33. However, the present invention isnot limited to this, and the base electrode layer 30 including aplurality of regions may be manufactured by adjusting the material andthe temperature profile, for example.

In the present preferred embodiment, the glass G includes Ba. However,the glass G may not include Ba. In this case, the protective layer 33does not include Ba. However, the protective layer 33 includes S by theprocess liquid including S.

In the present preferred embodiment, the Cu paste having a smallparticle size is used in the barrel step when the first region 30 a ofthe base electrode layer 30. However, the present invention is notlimited thereto. In order to improve the connection ratio, for example,either one of performing the barrel step or using a Cu paste having asmall size may be used.

In the present preferred embodiment, the multilayer ceramic capacitor 1is manufactured by manufacturing the laminate chip 10 following whichthe side gap portions 20 are affixed on both sides of the laminate chip10. However, the present invention is not limited to this, and the sidegap portions 20 may be manufactured together at the time ofmanufacturing the laminate chip 10.

In the present preferred embodiment, two plated layers are provided.However, the present invention is not limited thereto, and the platedlayer may include a single layer.

Furthermore, the size of the multilayer ceramic capacitor 1, and thethickness and the number of layers of the internal electrode layers 15,the dielectric layers 14, the outer layer portions 12, and the externalelectrodes 3, which are specified in the present preferred embodiment,are not limited to the numerical values described, and may varytherefrom.

Furthermore, the components included in each layer are not limited tothose described in the present preferred embodiment.

While preferred embodiments of the present invention have been describedabove, it is to be understood that variations and modifications will beapparent to those skilled in the art without departing from the scopeand spirit of the present invention. The scope of the present invention,therefore, is to be determined solely by the following claims.

What is claimed is:
 1. A multilayer ceramic capacitor comprising: amultilayer body including: an inner layer portion including dielectriclayers and internal electrode layers alternately laminated therein; twoouter layer portions respectively provided on both sides of the innerlayer portion in a lamination direction; and two side gap portionsrespectively provided on both side surfaces of the inner layer portionand the outer layer portions, in a width direction intersecting thelamination direction; and external electrodes respectively provided onboth end surfaces of the multilayer body in a length directionintersecting the lamination direction and the width direction, and eachconnected to the internal electrode layers; wherein nickel and magnesiumare segregated between the side gap portions and the outer layerportions.
 2. The multilayer ceramic capacitor according to claim 1,wherein nickel is segregated in the outer layer portions.
 3. Themultilayer ceramic capacitor according to claim 1, wherein magnesium issegregated in both side portions of the internal electrode layers in thewidth direction.
 4. The multilayer ceramic capacitor according to claim1, wherein each of the outer layer portions has a thickness of about 9.5μm or more and about 30 μm or less.
 5. The multilayer ceramic capacitoraccording to claim 1, wherein a dimension of the multilayer ceramiccapacitor in the length direction is about 0.2 mm or more and about 1.2mm or less, a dimension of the multilayer ceramic capacitor in a widthdirection intersecting the length direction is about 0.1 mm or more andabout 0.7 mm or less, and a dimension of the multilayer ceramiccapacitor in the lamination direction is about 0.1 mm or more and about0.7 mm or less.
 6. The multilayer ceramic capacitor according to claim1, wherein each of the dielectric layers has a thickness of about 0.4 μmor more and about 1.0 μm or less.
 7. The multilayer ceramic capacitoraccording to claim 1, wherein each of the dielectric layers has athickness of about 0.4 μm or more and about 0.6 μm or less.
 8. Themultilayer ceramic capacitor according to claim 1, wherein thedielectric layers include BaTiO₃ as a main component.
 9. The multilayerceramic capacitor according to claim 1, wherein a number of thedielectric layers is 15 or more and 700 or less.
 10. The multilayerceramic capacitor according to claim 1, wherein the dielectric layers donot include Ni.
 11. The multilayer ceramic capacitor according to claim1, wherein each of the internal electrode layers has a thickness ofabout 0.2 μm or more and about 0.8 μm or less.
 12. The multilayerceramic capacitor according to claim 1, wherein each of the internalelectrode layers is made of Cu, Ag, Pd, Ag—Pd, or Au.
 13. The multilayerceramic capacitor according to claim 12, wherein a Sn-layer is providedon a surface of each of the internal electrode layers.
 14. Themultilayer ceramic capacitor according to claim 1, wherein each of theouter layer portions has a thickness of about 9.5 μm or more and about20 μm or less.